Researchers use alkylammonium chlorides to regulate development of perovskite layers as well as achieve 26.08% effectiveness PSC

Mar 2, 2023 03:41 PM ET
  • Scientists at South Korea's Ulsan National Institute of Science and Technology (UNIST), Chonnam National University and also Pohang University of Science and also Technology (POSTECH) have actually created a special perovskite solar cell that utilizes alkylammonium chloride (RACI) to regulate the development of defects in the perovskite layer.
Researchers use alkylammonium chlorides to regulate development of perovskite layers as well as achieve 26.08% effectiveness PSC
Image: scitechdaily.com

The US National Renewable Energy Laboratory (NREL) has accredited the South Oriental study team's cell's 25.73% performance. The champion tool constructed by the researchers reached an effectiveness of 26.08%.

" Alkylammonium chloride, which is dequantized at the formation phase while integrating with perovskite parts, was made use of," stated researcher Sang Il Seok. "This optimum combination with Alkyl was also able to ideally control the price of volatilization with solvent during layer and warm therapy of perovskite forerunner solution."

The team built the cell with formamidinium lead iodide (FAPbI3) metal halide perovskite, which offers exceptional thermal stability and also a narrow bandgap. The brand-new procedure allows the development of a dense perovskite film with good crystallinity, they claimed. They investigated the surface morphology of the film through grazing event wide-angle X-ray diffraction as well as scanning electron microscopy.

"RACl included in the precursor option was thought to be easily volatilized during finishing and annealing," the researchers explained.

The film was examined in a perovskite cell and located that it achieved a power conversion performance of 26.08%, an open-circuit voltage of 1.18 V, a short-circuit current of 25.7 mA/cm2, as well as a fill factor of 86.15%. When evaluated by NREL specialists, the gadget achieved a certified performance of 25.73%.

"This research is really significant, as it analyzes the condensation process of perovskite with halide anions in real time with the UNIST-PAL Beamline of Pohang Accelerator Laboratory," stated scientist Tae Joo Shin from UNIST.




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