Understanding solid state degradation

Aug 5, 2019 09:36 PM ET
  • Scientists at the U.K.’s Faraday Institution have been able to observe degradation mechanisms at the lithium metal anode in a solid state battery, and made several discoveries which could improve the performance and design of future solid-state lithium-ion batteries.
Understanding solid state degradation
Image: Angel Xavier Viera-Vargas/Flickr
A team of scientists working at Oxford University in the U.K. have made valuable insights into the performance of solid-state lithium-ion batteries.

By improving our understanding of the mechanisms that cause solid state batteries to fail under frequent cycling (a barrier to commercial production), the research could allow scientists to pursue new battery designs that avoid or mitigate these failure mechanisms.

In a paper, “Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells,” published in the journal Nature Materials, the scientists observed the formation of dendrites – branching networks of lithium that grow through the electrolyte – and voids, which reduce the area of contact between the anode and the electrolyte.

“It is key to break down the scientific barriers that prevent the progression to market of technologies that will enable our vision of the future of mobility. The study by Oxford researchers is one early example of a scientific advance that the Faraday Institution was set up to drive,” said Tony Harper, director of the ISCF Faraday Battery Challenge at U.K. Research & Innovation.

The researchers worked with a three-electrode battery, in order to better be able to separate lithium plating from stripping, using Argyrodyte (Li6PS5Cl) as an electrolyte.

Image: Nature Materials 2019

They found that keeping current density low is key to avoiding these undesirable mechanisms. “When the stripping current density removes Li from the interface faster than it can be replenished, voids form in the Li at the interface and accumulate on cycling, increasing the local current density at the interface and ultimately leading to dendrite formation on plating, short circuit and cell death,” explains the paper’s abstract. “This occurs even when the overall current density is considerably below the threshold for dendrite formation on plating.”

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