Next-generation monograin layer solar cells containing silver

Dec 11, 2019 12:05 PM ET
  • The scientific team from TalTech has finally succeeded in improving the performance of their innovative photovoltaic cells by replacing part of copper in absorbing layer with silver.
Next-generation monograin layer solar cells containing silver
Image: Professor Jüri Krustok

The scientists from Tallinn University of Technology are developing innovative PV technology — a mono-grain layer cell. The R&D is aimed at creating an advanced solar device – a thin film compound semiconductor cell. 

Thin film cells comprise a few thin semiconducting layers. In order to achieve high conversion efficiency, the semiconducting material used should possess high light absorbing properties. Silicon is not a successful nominee because of low light absorption, as a result of which an absorbing layer must be thick enough.

The Tallinn-based research team is working on development of alternative compound semiconductors – kesterites. These minerals are both characterized by high light absorbing properties and consist of cheap widespread elements. Production of Cu2ZnSn(Se,S)4 is based on an exclusive mono-grain powder technological process. 

Mono-grain powder is made of unique micro-crystals forming tiny cells parallel-connected in a big module. Such solar panels feature a wide range of benefits compared to conventional silicon modules, such as lightweightness, flexibility, eco-friendliness and cost-efficiency (which does not compromise their transparency). 

To maximize the kesterite-based cell performance, the scientists have tried and replaced 1 percent of copper contained in an absorbing layer with silver. As a result, they have achieved 2 percent improvement – 8.7 compared to 6.6 percent. 

The mono-grain layer tech is implemented by Crystalsol (Austria- and Estonia-based joint venture). For scaling the technology to commercial level, the cell performance must reach at least 15 percent.


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