A technique to attain amorphous silicon solar cells with over 25% efficiency

Jun 8, 2022 12:36 PM ET
  • Recently, designers worldwide have actually been creating various new technologies to generate and store energy more sustainably. These technologies consist of solar or photovoltaic cells, electrical tools that can convert the light from the sun right into electrical energy.
A technique to attain amorphous silicon solar cells with over 25% efficiency
Image: Liu et al. (Nature Energy, 2022)

2 encouraging sorts of solar cells are silicon heterojunction (SHJ) solar cells and perovskite/SHJ tandem solar cells. Both of these classes of solar cells are fabricated using hydrogenated amorphous silicon (a-Si: H), the non-crystalline form of silicon, which is additionally frequently utilized to construct thin-film transistors, batteries and LCD screens.

A-Si: H has actually been used to develop photovoltaics for countless years, because of its low flaw thickness, tunable conduction and various other advantages. As this material's benefits heavily depend on the configurations of hydrogen and silicon in 3D room, engineers have to have the ability to manage the material's microscopic structure with high degrees of precision to make extremely doing gadgets.

In the past, materials researchers have tried to dope amorphous silicon utilizing the metalloid chemical aspect boron to harvest light from the sunlight more effectively. Nevertheless, up until now the majority of them accomplished poor and undependable results.

Scientists at the Chinese Academy of Sciences (CAS), Zhongwei New Energy, and King Abdullah University of Science and Technology (KAUST) have just recently presented a brand-new method that might substantially improve the effectiveness of Si: H thin films doped making use of boron. This technique, introduced in a paper released in Nature Energy, essentially requires light saturating the films.

" Due to the extremely reduced efficient doping performance of trivalent boron in amorphous tetravalent silicon, light harvesting of SHJ gadgets is restricted by their fill variables (FFs), a straight metric of the fee carrier transportation," Wenzhu Liu and his colleagues wrote in their paper. "It is difficult but important to create very conductive doped a-Si: H with very little FF losses. We report that light soaking can efficiently enhance the dark conductance of boron-doped a-Si; H thin films."

In their experiments, Liu and his colleagues discovered that light can induce diffusion and the jumping of weakly bound hydrogen atoms in a-Si: H. This consequently triggers boron doping, enhancing the product's light harvesting capacities. The result reported by the researchers is relatively easy to fix and the team located that the product's dark conductivity spontaneously lowers over time, when the solar cells are no more brightened.

Liu and his colleagues checked the performance of their strategy by using it to increase the performance of SHJ solar cells. They then evaluated the performance of their solar cells at a common temperature level of 25 ° C, utilizing a solar light simulator.

Overall, the solar cells they doped utilizing their method exhibited a remarkable certified total-area power conversion efficiency of 25.18% with an FF of 85.42% on a 244.63 cm2 wafer. These outcomes are extremely appealing and could be additionally boosted in their following studies.

The current work by this group of scientists could have essential ramifications for the growth of SHJ solar cells and silicon-based photovoltaics. In the future, the method they recommended could be made use of to boost the light harvesting residential or commercial properties of both existing and freshly created solar technologies.


SOLAR DIRECTORY
Solar Installers, Manufacturers